Indenyl Zirconium Dinitrogen Chemistry: N2 Coordination to an Isolated Zirconium Sandwich and Synthesis of Side-on, End-on Dinitrogen Compounds

D Pun, E Lobkovsky, PJ Chirik

文献索引：Pun, Doris; Lobkovsky, Emil; Chirik, Paul J. Journal of the American Chemical Society, 2008 , vol. 130, # 18 p. 6047 - 6054

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被引用次数: 34

摘要

Exposure of the isolable zirconocene sandwich compounds,(η5-C5Me5)(η5-C9H5-1-R1-3- R2) Zr (R1= Me, iPr, tBu; R2= Me) to one atmosphere of dinitrogen resulted in N2 coordination. X-ray diffraction and NMR spectroscopy establish that the resulting dimeric ...