Neutral Dimethylzirconocene Complexes as Initiators for the Ring??Opening Polymerization of ϵ??Caprolactone

…, R Fernández??Galán, I López??Solera…

文献索引：Villasenor, Elena; Gutierrez-Gonzalez, Ruben; Carrillo-Hermosilla, Fernando; Fernandez-Galan, Rafael; Lopez-Solera, Isabel; Fernandez-Pacheco, Ana Rodriguez; Antinolo, Antonio European Journal of Inorganic Chemistry, 2013 , # 7 p. 1184 - 1196

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被引用次数: 1

摘要

Abstract The synthesis, structures, and ring-opening polymerization (ROP) activity of new dimethyl-ansa-and-non-ansa-zirconocene complexes are reported. The substituted indene precursors 1-C 9 H 7 R [R= CH 3 (1), CH 2 Ph (2) and C 2 H 4 (C 4 H 7 O 2)(3)] were synthesised by treating RBr [R= CH 2 Ph and C 2 H 4 (C 4 H 7 O 2)] or MeI with indenyllithium. Likewise, bridged indenyl/cyclopentadiene compounds [Me 2 Si (3-C 9 H 6 ...