Aromatic substitution. 58. Boron tris (triflate)-catalyzed adamantylation of benzene and toluene with 1-and 2-haloadamantanes and adamantanoyl chlorides. …

GA Olah, O Farooq, SMF Farnia…

文献索引：Olah, George A.; Farooq, Omar; Farnia, S. Morteza F.; Wu, An-hsiang Journal of Organic Chemistry, 1990 , vol. 55, # 5 p. 1516 - 1522

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被引用次数: 15

摘要

Interconversion of isomeric 2-phenyl (tolyl) adamantanes into the corresponding 1-phenyl (toly1) adamantanes was observed through intermolecular isomerization involving adamantyl cations and adamantane, which is formed in significant amount in all the reactions. Decarbonylative alkylation of aromatics with adamantanoyl chlorides was also investigated. Adamantanoylated aromatics were formed only in very low amounts, the ...