N-substituted hexamethyldisilazanes as new substances for the synthesis of functional films in the system Si-Ge-CNH

…, AA Titov, VI Rakhlin, IP Tsyrendorzhieva…

文献索引：Sysoev; Nikulina; Kolontaeva; Kosinova; Titov; Rakhlin; Tsyrendorzhieva; Lis; Voronkov Russian Journal of General Chemistry, 2011 , vol. 81, # 12 p. 2501 - 2505

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摘要

Abstract N-Organylbis (trimethylsilyl) amines of the general formula RN (SiMe 3) 2 (R= Me 3 Si, Et 3 Ge) were synthesized by reaction of sodium bis (trimethylsilyl) amide with the corresponding trialkylsilyl (germyl) halide. Their IR, UV, and 1 H, 13 C, and 29 Si NMR spectra were studied, and saturated vapor pressures and thermal stabilities were determined. The possibility of using the RN (SiMe 3) 2 compounds as precursors in ...