Synthesis of novel expanded calixphyrins: anion binding properties of a calix [6] phyrin with a deep cavity

C Bucher, RS Zimmerman, V Lynch…

文献索引：Bucher; Zimmerman; Lynch; Kral; Sessler Journal of the American Chemical Society, 2001 , vol. 123, # 9 p. 2099 - 2100

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被引用次数: 100

摘要

Chemical hybrids of the porphyrins and calixpyrroles, calix-[n] phyrins, are polypyrrolic macrocycles that contain at least one sp3 hybridized meso-like bridging carbon atom. While examples of calix [4] phyrin derivatives, represented by such classic structures as the phlorins, 1 isoporphyrins, 2 5, 10-or 5, 15-dihydroporphyrins, 3 and porphomethenes, 4 abound, the chemistry of higher order calix-[n] phyrins (n> 4) remains virtually unexplored. ...