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Enantioselective total synthesis of (-)-taxol

H Kusama, R Hara, S Kawahara…

文献索引：Journal of the American Chemical Society, , vol. 122, # 16 p. 3811 - 3820

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被引用次数: 145

摘要

... Journal of the ... 2000, 122 (16), pp 3811–3820. DOI: 10.1021/ja9939439. Publication Date (Web): April 5, 2000. Copyright © 2000 American Chemical Society. ... taxol and its structural analogues are expected to bring much greater advances both in synthetic organic chemistry and in ...

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(3aS,3a1S,6aS,7S,8S,10S,13aS)-10-((tert-butyldimethylsilyl)oxy)-7,8-dihydroxy-11,14,14-trimethyl-4,5,7,8,9,10,13,13a-octahydro-1,3-dioxa-3a1,6a:8,12-dimethanocyclodeca[de]naphthalene-2,6(3aH)-dione结构式

219780-79-7

(3aS,3a1S,6aS,7...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,5S,9S,9aS,10S,13bS)-5-((tert-butyldimethylsilyl)oxy)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9,9a,10,11,12,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-9,10,13-triol结构式

219780-81-1

(2S,3aS,5S,9S,9...

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紫杉醇结构式

33069-62-4

紫杉醇

未登录结构式

219780-80-0

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紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,5S,9S,9aS,10S,13aS,13bS)-5-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-6,15,15-trimethyl-2-phenyl-4,5,8,9,11,12-hexahydro-13bH-3a,7:9a,13a-dimethanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13(10H)-one结构式

219780-49-1

(2S,3aS,5S,9S,9...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(3aS,5S,9S,9aS,10S,13aS,13bS)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-6,15,15-trimethyl-4,5,8,9,11,12-hexahydro-13bH-3a,7:9a,13a-dimethanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-13(10H)-one结构式

219780-77-5

(3aS,5S,9S,9aS,...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(3aS,3a1S,7S,8aS,11aS,11bS,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-3a,4,7,8,14,14a-hexahydro-11aH-1,3,9,11-tetraoxa-10-sila-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalene-2,12(13H)-dione结构式

219780-78-6

(3aS,3a1S,7S,8a...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(3aS,7S,8aS,11aS,12R,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,15,15-trimethyl-2-phenyl-3a,7,8,11a,12,13,14,14a-octahydro-4H-1,3,9,11-tetraoxa-10-sila-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-ol结构式

219780-47-9

(3aS,7S,8aS,11a...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,3a1S,7S,8aS,11aS,11bS,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-2-phenyl-3a,4,7,8,14,14a-hexahydro-11aH-1,3,9,11-tetraoxa-10-sila-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12(13H)-one结构式

219780-48-0

(2S,3aS,3a1S,7S...

~%

紫杉醇结构式

33069-62-4

紫杉醇

未登录结构式

219780-76-4

未登录

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紫杉醇结构式

33069-62-4

紫杉醇

7-O-(2,2,2-三氯乙氧基羰基)浆果赤霉素 III结构式

103150-33-0

7-O-(2,2,2-三氯乙氧...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,5S,9S,9aS,10S,13aR,13bS)-5,9,10-trihydroxy-6,9a,14,14-tetramethyl-2-phenyl-4,5,8,9,9a,10,11,12,13a,13b-decahydro-13H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-one结构式

219780-52-6

(2S,3aS,5S,9S,9...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-51-5

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紫杉醇结构式

33069-62-4

紫杉醇

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219780-84-4

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紫杉醇结构式

33069-62-4

紫杉醇

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219780-86-6

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~%

紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,5S,9aS,10S,13aR,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9a,10,11,12,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-9,13-dione结构式

219780-53-7

(2S,3aS,5S,9aS,...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-55-9

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紫杉醇结构式

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219780-89-9

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219780-54-8

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紫杉醇结构式

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紫杉醇结构式

33069-62-4

紫杉醇

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219780-92-4

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紫杉醇结构式

33069-62-4

紫杉醇

(2S,3aS,5S,9aS,10S,13aR,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-9-oxo-2-phenyl-5,8,9,9a,10,11,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl trifluoromethanesulfonate结构式

219780-87-7

(2S,3aS,5S,9aS,...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-91-3

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紫杉醇结构式

33069-62-4

紫杉醇

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219780-58-2

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紫杉醇结构式

33069-62-4

紫杉醇

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272440-14-9

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紫杉醇结构式

33069-62-4

紫杉醇

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272440-02-5

~%

紫杉醇结构式

33069-62-4

紫杉醇

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272440-06-9

~%

紫杉醇结构式

33069-62-4

紫杉醇

结构式

272440-03-6

~%

紫杉醇结构式

33069-62-4

紫杉醇

((2S,3aS,3a1R,7S,8aS,10S,11aS,14aS)-7,12-bis((tert-butyldimethylsilyl)oxy)-2-(4-methoxyphenyl)-6,15,15-trimethyl-10-phenyl-3a,4,7,8,11a,13,14,14a-octahydro-3a1H-1,3,9,11-tetraoxa-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-3a1-yl)methanol结构式

272440-05-8

((2S,3aS,3a1R,7...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(3aS,3a1S,7S,8aS,10S,11aS,11bR,14aS)-7-hydroxy-3a1,6,15,15-tetramethyl-2,10-diphenyl-3a,3a1,4,7,8,11a,11b,13,14,14a-decahydro-12H-1,3,9,11-tetraoxa-2-bora-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-one结构式

219780-82-2

(3aS,3a1S,7S,8a...

~%

紫杉醇结构式

33069-62-4

紫杉醇

(3aS,3a1S,7S,8aS,10S,11aS,11bR,14aS)-7-((tert-butyldimethylsilyl)oxy)-3a1,6,15,15-tetramethyl-2,10-diphenyl-3a,3a1,4,7,8,11a,11b,13,14,14a-decahydro-12H-1,3,9,11-tetraoxa-2-bora-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-one结构式

219780-83-3

(3aS,3a1S,7S,8a...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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149249-91-2

(3R,4S)-1-苯甲酰-3...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-94-6

(2aR,4S,4aS,6R,...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-97-9

(2aR,4S,4aS,6R,...

~%

紫杉醇结构式

33069-62-4

紫杉醇

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219780-95-7

~%

紫杉醇结构式

33069-62-4

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结构式

219780-96-8

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33069-62-4

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未登录结构式

219780-59-3

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33069-62-4

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未登录结构式

189441-63-2

未登录

~%

紫杉醇结构式

33069-62-4

紫杉醇


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