Caro's acid supported on silica gel. Part VI. A mild reagent for regeneration of carbonyl compounds from acetals, ketals, and 1, 1-diacetates

MM Lakouraj, M Tajbakhsh, V Khojasteh…

文献索引：Lakouraj; Tajbakhsh; Khojasteh; Gholami Phosphorus, Sulfur and Silicon and the Related Elements, 2004 , vol. 179, # 12 p. 2645 - 2651

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被引用次数: 4

摘要

Efficient conversion of acetals, ketals, and diacetates to carbonyl compounds is described using Caro's acid supported on silica gel. The deacetalization reactions are carried out in acetonitrile at room temperature. Reaction of diacetates is performed in refluxing dichloromethane, and their parent carbonyl compounds are obtained in good-to-excellent yields.