Solid-phase oxidation of organic compounds with benzyltriphenylphosphonium dichromate

…, I Mohammadpoor-Baltork

文献索引：Hajipour; Mohammadpoor-Baltork, Iraj Phosphorus, Sulfur and Silicon and Related Elements, 2000 , vol. 164, p. 145 - 151

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被引用次数: 14

摘要

Abstract Benzyltriphenylphosphonium dichromate could be used for oxidation of organic compounds such as alcohols, thiols and sulfides to the corresponding carbonyl, disulfide and sulfoxide derivatives under solid-phase conditions. This reagent is very easily prepared from an aqueous solution of benzyltriphenylphosphonium chloride with CrO3 in 3 N HCI at room temperature. The reagent, is a stable orange powder, which may be stored for month ...