Journal of the American Chemical Society

Iron and ruthenium carbonyl catalyzed reductive carbonylation of nitro compounds by sodium methoxide. A significant effect of the metal on the reaction course

H Alper, KE Hashem

文献索引：Alper, Howard; Hashem, Khaled E. Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6514 - 6515

被引用次数: 54

摘要

8 prepared by coinjection, where 8 can bind to both interior and exterior surfaces of the vesicles, displayed biphasic kinetics for cleavage of 8 (method A), with k,'(96% of reaction)= 2.5 sl and k,”= 0.099 sl. Vesicular 1, prepared by method B and subsequently reacted with 8, displayed only monophasic kinetics (299% of reaction) with k,'= 2.4 sI.** Note that k $ is identical

~74%

~57%

~60%

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~59%

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~38%

~37%

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~18%

~17%

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~18%

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~62%

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~62%

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~31%

~32%

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~18%

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~4%

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~17%

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~35%

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Iron and ruthenium carbonyl catalyzed reductive carbonylatio...

[Journal of the American Chemical Society, , vol. 103, # 21 p. 6514 - 6515]