A Mild Catalytic Oxidation System: Ruthenium Porphyrin and 2, 6??Dichloropyridine N??Oxide Applied for Alkene Dihydroxylation

…, PR Li, G Jiang, CM Che, J Chen

文献索引：Hu, Wen-Xiang; Li, Pei-Rong; Jiang, Gaoxi; Che, Chi-Ming; Chen, Jian Advanced Synthesis and Catalysis, 2010 , vol. 352, # 18 p. 3190 - 3194

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被引用次数: 1

摘要

Abstract A new method was developed to transform alkenes into three types of functional molecules, including epoxides, aldehydes and 1, 2-diols by using dichlororuthenium (IV) meso-tetrakis (2, 6-dichlorophenyl) porphyrin [Ru (IV)(TDCPP) Cl 2] as catalyst and 2, 6- dichloropyridine N-oxide (Cl 2 pyNO) as the oxidant, in which the 1, 2-diols were afforded via “one-pot” reactions in moderate yields.