ADDITION REACTIONS OF PHOSPHORUS HALIDES. IV. THE ACTION OF THE TRICHLORIDE ON SATURATED ALDEHYDES AND KETONES.

JB Conant, AD MacDonald…

文献索引：Conant; McDonald; Kinney Journal of the American Chemical Society, 1921 , vol. 43, p. 1932

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被引用次数: 16

摘要

Summary. 1. Vinyl mercury oxychloride is obtained when alkaline solutions of acetaldehyde are treated with mercuric chloride. 2. The yield of vinyl mercury oxychloride is proportional to the concentration of the alkali present, showing that the production of vinyl alcohol is likewise proportional to the concentration of the alkali. 3. Since the formation of vinyl alcohol is necessary to account for the'presence of oxalic acid in the oxidation of ethyl alcohol and ...