Tetrahedron

The asymmetric hydroboration of simple alkenylsilanes: chiral α-silylalkyl-boranes and alcohols

JA Soderquist, SJH Lee

文献索引：Soderquist, John A.; Lee, Shwn-Ji Hwang Tetrahedron, 1988 , vol. 44, # 13 p. 4033 - 4042

全文：HTML全文

被引用次数: 20

摘要

The detailed study of the asymmetric hydroboration of various vinyl-silanes with monoisopinocampheylborane (IPCBH2) is presented. In all cases, β-substitution on the vinylsilane gives monomeric dialkylborane adducts with the boryl group α to the silicon.