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Crown cation complex effects. 12. Dissolution and complexation of arenediazonium cations in nonpolar media. An assessment of solvent effects and reactivity by …

SH Korzeniowski, A Leopold, JR Beadle…

文献索引:Korzeniowski, Stephen H.; Leopold, Ahuva; Beadle, James R.; Ahern, Michael F.; Sheppard, William A.; et al. Journal of Organic Chemistry, 1981 ,  vol. 46,  # 10  p. 2153 - 2159

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被引用次数: 36

摘要

A number of arenediazonium salts (largely tetrafluoroborates) have been surveyed to determine their solubility properties and the influence of crown ethers and quaternary ammonium salts thereupon. Analysis has been by a variety of spectral techniques including IR and'H, lac, and'9 NMR spectroscopy. These studies reveal that solvation of the diazo linkage is not the major factor in determining solubility and that a variety of cosolvents may ...