e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Crown cation complex effects. 12. Dissolution and complexation of arenediazonium cations in nonpolar media. An assessment of solvent effects and reactivity by …
SH Korzeniowski, A Leopold, JR Beadle…
Index: Korzeniowski, Stephen H.; Leopold, Ahuva; Beadle, James R.; Ahern, Michael F.; Sheppard, William A.; et al. Journal of Organic Chemistry, 1981 , vol. 46, # 10 p. 2153 - 2159
A number of arenediazonium salts (largely tetrafluoroborates) have been surveyed to determine their solubility properties and the influence of crown ethers and quaternary ammonium salts thereupon. Analysis has been by a variety of spectral techniques including IR and'H, lac, and'9 NMR spectroscopy. These studies reveal that solvation of the diazo linkage is not the major factor in determining solubility and that a variety of cosolvents may ...