Tetrahedron

Triene electrocyclizations: Some structure reactivity relations

EN Marvell, G Caple, C Delphey, J Platt, N Polston…

文献索引：Marvell,E.N. et al. Tetrahedron, 1973 , vol. 29, p. 3797 - 3806

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被引用次数: 23

摘要

Two stereoselective routes for the synthesis of trienes having a central cis double bond have been devised. These were employed for the synthesis of (Z)-1-(cyclohexen-1-yl)-1, 3- butadiene (1),(Z, E)-1-(cyclohexen-1-yl)-1, 3-pentadiene (2),(Z, Z)-1-(cyclohexen-1-yl)-1, 3- pentadiene (3), 1, 2-divinyleyclohexene (4),(E, Z)-1-phenyl-1, 3, 5-hexatriene (5),(Z, Z)-1- phenyl-1, 3, 5-hexatriene (6) and (E, Z)-1-(p-chlorophenyl)-1, 3, 5-hexatriene (7). Rates of ...