Tetrahedron letters

Synthesis of brominated compounds. A convenient molybdenum-catalyzed procedure inspired by the mode of action of haloperoxidases

V Conte, F Di Furia, S Moro

文献索引：Conte, Valeria; Di Furia, Fulvio; Moro, Stefano Tetrahedron Letters, 1996 , vol. 37, # 47 p. 8609 - 8612

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被引用次数: 35

摘要

A two-phase (CHCl 3H 2O) procedure for the synthesis of halogenated compounds has recently been developed. Such procedure mimics the mode of action of the enzymes haloperoxidases which contain vanadium in their active center. We have investigated the possibility to substitute vanadium with molybdenum. The molybdenum-based reactions show some advantages over the vanadium-based ones. In fact reaction times are shorter ...