Stable carbocations. CLXIII. Complexing ionization, and fragmentative alkylcarbenium ion formation from alkyl haloformates, thiolhaloformates, and halosulfites with …
GA Olah, P Schilling, JM Bollinger…
文献索引：Olah,G.A. et al. Journal of the American Chemical Society, 1974 , vol. 96, p. 2221 - 2228
Abstract: Alkyl (aryl) haloformates, thiolhaloformates, and halosulfites form complexes with antimony pentafluoride in SO2 or SOzCIF solution. The complexes of alkyl thiolhaloformates gave alkylthiolcarbonyl cations through subsequent ionization, although complexes of alkyl haloformates and halosulfites lost immediately COz and SOz, respectively, to give corresponding alkyl fluoroantimonates. Thus, the intermediate alkoxycarbonyl and ...
