The Journal of Organic Chemistry

Chemistry of dioxiranes. 22. Reaction of dimethyldioxirane with alkynes

RW Murray, M Singh

文献索引：Murray, Robert W.; Singh, Megh Journal of Organic Chemistry, 1993 , vol. 58, # 19 p. 5076 - 5080

被引用次数: 33

摘要

The reaction of dimethyldioxirane with several alkynes gives products which are conveniently rationalized by postulating the intermediacy of oxirenes and oxocarbenes. The latter serve as precursors to H atom or methyl group migration products, as well as to cyclopropane insertion products in some cases. Alkenes, derived from some of these carbene reactions, are partially converted to epoxides.

999-78-0

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