Bulletin of the Chemical Society of Japan

The Reaction of Monoketones with Manganese (III) Acetate

M Okano, T Aratani

文献索引：Okano,M.; Aratani,T. Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 2811 - 2814

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被引用次数: 19

摘要

When acetone, ethyl methyl ketone (EMK), and cyclohexanone were heated with manganese (III) acetate dihydrate in a mixed solvent of glacial acetic acid and acetic anhydride at 100° C, acetoxy ketones were obtained as common products. Furthermore, ketone dimers (1, 4-diketones) were obtained from acetone and cyclohexanone, which also gave 1, 2, 3, 4-tetrahydrodibenzofuran. When mixtures of these ketones and 1-hexene ...