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Steric effects in coordination of 1, 1, 1-tris (dimethylaminomethyl) ethane and of 1, 1, 1-tris (monomethylaminomethyl) ethane. I. Zinc (II) complexes

WJ Kasowski, JC Bailar Jr

文献索引:Kasowski,W.J.; Bailar,J.C. Journal of the American Chemical Society, 1969 , vol. 91, p. 3212 - 3218

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被引用次数: 16

摘要

Abstract: Steric effects in coordination of the new tripod ligand 1, 1, 1-tris (dimethylaminomethy1) ethane (TTN) and of l, l, l-tris (monomethylaminomethy1) ethane (TSN) have been investigated by the preparation and characterization of their zinc chloride and zinc bromide complexes. The stereochemistry of the complexes has been established on the basis of data from 'H nuclear magnetic resonance (nmr) spectroscopy, infrared ...