Abstract Novel trinuclear coordinated ligands were designed using three of 1, 4, 7- triazacyclononane moieties with a tribromo linker. These ligands show greater capability and potency in association with various metal ions. Tris (diisopropyl-1, 4, 7- triazacyclononanes) ethane (2) associated with Cu 2+ and Ce 4+ ions shows better reactivity to achieve DNA hydrolysis at 37 C at pH 8 for 5 hr. Using high resolution of ...
[Mahapatra, Samiran; Halfen, Jason A.; Wilkinson, Elizabeth C.; Pan, Gaofeng; Wang, Xuedong; Young Jr., Victor G.; Cramer, Christopher J.; Que Jr., Lawrence; Tolman, William B. Journal of the American Chemical Society, 1996 , vol. 118, # 46 p. 11555 - 11574]