The reduction of specific disulfides with titanium (III) chloride

HA Akers, MC Vang, TD Updike

文献索引：Akers, Hugh A.; Vang, Meng C.; Updike, Tracie D. Canadian Journal of Chemistry, 1987 , vol. 65, p. 1364 - 1366

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被引用次数: 8

摘要

The reaction between titanium (III) chloride and disulfides was investigated. Aryl and alkyl disulfides did not react while heterocyclic aromatic disulfides with a nitrogen α to the sulfur were reduced to the corresponding thiols. Products were identified and characterized by nuclear magnetic resonance and infrared spectra, and melting point comparisons with authentic compounds. The reductions occurred only in the presence of citrate and were ...