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The Journal of Organic Chemistry

A convenient synthesis of N-vinylpyridinium perchlorate and a study of N-vinylpyridinium cations as Michael reaction acceptors

AR Katritzky, O Rubio

文献索引:Katritzky, Alan R.; Rubio, Olga Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4017 - 4021

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被引用次数: 17

摘要

Katritzky and Rubio system 1 has been its inaccessibility, preparation necessitating the use of Ag20. By an application of our procedure previously reported for the 2, 4, 6-trisubstituted analogues, we now describe a convenient route to l in good yield together with a study of its chemistry, and in particular, concrete evidence for considerable mutual interaction between the pyridinium ring and the vinyl group in both 1 and the triphenyl analogue 2.