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Journal of Organometallic Chemistry

The mechanism of the acid-catalyzed propanolysis of 2-sila-1, 3-dioxolanes

B Bøe

文献索引:Boe,B. Journal of Organometallic Chemistry, 1972 , vol. 43, p. 275 - 284

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被引用次数: 7

摘要

Abstract Hexamethyl-2-sila-1, 3-dioxolane reacts with an excess of isopropanol according to a first-order rate law. The reaction is acid-catalyzed, with a linear relation between the rate constant and the concentration of catalyst. The ring opening is fast, and is followed by a rate- determining step to give the products.