DIE KINETIK DER REAKTION VON 2-PROPYLCHLORFORMIAT MIT ALKALIRHODANIDEN. BETEILIGUNG DES SCN−-IONS UND DES IONENPAARES (MSCN) AN …

VV Dragalov, VE Lavrov

文献索引：Dragalov, V. V.; Lavrov, V. E. Phosphorus and Sulfur and the Related Elements, 1988 , vol. 37, p. 107 - 110

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摘要

Abstract When isopropylcarbonylthiocyanate and isothiocyanate are formed from isopropylchloroformate and alkalirhodanides, rhodanide ions and ion pairs react simultaneously. The rate constants with SCN−-ions (ki) and with ion pairs MSCN (sk ip) have been determined at various temperatures and with different alkali ions. The values of ki are equal for the rhodanides studied, whereas the values of sk ip are growing in the sequence ...