Journal of organometallic chemistry

Das chlorsilylsubstituierte Silanimin t Bu 2 Si N SiCl t Bu 2

HW Lerner, N Wiberg, JW Bats

文献索引：Lerner, Hans-Wolfram; Wiberg, Nils; Bats, Jan W. Journal of Organometallic Chemistry, 2005 , vol. 690, # 17 p. 3898 - 3907

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摘要

In the thermolysis of the silaterazolines silatetrazoline tBu2SiNSiCltBu2· tBu3SiN3 the silanimine tBu2SiNSiCltBu2 and the silyl azide tBu3SiN3 are formed quantitatively. The silanimine tBu2SiNSiCltBu2 has been trapped with Et3NHF, Me3NHCl, water, 1-butene, 2, 3- dimethyl-1, 3-butadiene, isobutene, methylvinyl ether, and tBu2SiClN3. The structure of the disiloxane (tBu2SiCl–NH–SitBu2) 2O and of the bis (di-tert-butylchlorsilyl)-substituted ...