Journal of Organometallic Chemistry

Miscellaneous reactions of some tris (trimethylsilyl) methylsilicon compounds

C Eaborn, FA Fattah

文献索引：Eaborn, Colin; Fattah, Faraedan A. Journal of Organometallic Chemistry, 1990 , vol. 396, # 1 p. 1 - 8

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被引用次数: 1

摘要

Abstract TsiSiMe 2 I (Tsi=(Me 3 Si) 3 C) gives TsiSiMe 2 OMe on treatment with AgBF 4 in MeOH but some TsiSiMe 2 F if an excess of CsF is also present. The triflates TsiSiMe 2 OSO 2 CF 3 and (Me 3 Si) 2 C (SiMePh 2 (SiMe 2 OSO 2 CF 3) react with alkali metal salts MX to give the corresponding derivatives TsiSiMe 2 X and (Me 3 Si) 2 C (SiMePh 2)(SiMe 2 X). TsiSiMe 2 OSO 2 CF 3 does not react with CF 3 CH 2 OH. The relative rates of reaction of ...