Consecutive Cyclization of Allylaminoalkene by Intramolecular Aminolithiation− Carbolithiation

…, A Kaneshige, T Ogata, H Baba, Y Yamamoto…

文献索引：Tsuchida, Susumu; Kaneshige, Atsunori; Ogata, Tokutaro; Baba, Hiromi; Yamamoto, Yasutomo; Tomioka, Kiyoshi Organic Letters, 2008 , vol. 10, # 16 p. 3635 - 3638

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被引用次数: 23

摘要

Consecutive cyclization of allylaminoalkenes by tandem aminolithiation− carbolithiation proceeded smoothly by using a lithium amide as a lithiating agent as well as protonating agent to give bicyclic amines, octahydroindolizine and hexahydro-1 H-pyrrolizine, in reasonably high yield and diastereoselectivity.