Synthesis of trans??1, trans??2, trans??3, and trans??4 Bisadducts of C60 by Regio??and Stereoselective Tether??Directed Remote Functionalization

…, P Seiler, O Lukoyanova, L Echegoyen…

文献索引：Sergeyev, Sergey; Schaer, Michael; Seiler, Paul; Lukoyanova, Olena; Echegoyen, Luis; Diederich, Francois Chemistry - A European Journal, 2005 , vol. 11, # 8 p. 2284 - 2294

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被引用次数: 61

摘要

Abstract The double Bingel reaction of fullerene C 60 with bismalonates attached to a Tröger base derived tether afforded trans-1, trans-2, trans-3, and trans-4 bisadducts with excellent regioselectivity. In particular, enantiomerically pure bisadducts with inherently chiral trans-2 or trans-3 addition patterns were prepared starting from enantiomerically pure bismalonates. The absolute configuration of the trans-2 and trans-3 bisadducts was established from ...