New Pd (II) Binuclear Complexes as Effective Catalysts in Oxidative-Heck Reaction Using Arylboronic Acid Derivatives

…, SM Shakil Hussain, M Fettouhi, B El Ali

文献索引：Suleiman, Rami; Shakil Hussain; Fettouhi, Mohammed; El Ali, Bassam Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2012 , vol. 42, # 6 p. 850 - 856

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摘要

A series of new binuclear Pd (II) complexes based on chelating diimines and bridging diphosphine or diimine ligands have been synthesized and characterized successfully. The formula of the new complexes are [Pd2 (mbyp) 2 (DPA) 2](PF6) 4 (1),[Pd2 (mbyp) 2 (DPE) 2](PF6) 4 (2),[Pd2 (mbyp) 2 (4, 4-byp) 2](PF6) 4 (3),[Pd2 (mbyp) 2 (t-pye) 2](PF6) 4 (4)[mbyp= 4, 4′-dimethyl-2, 2′-bipyridine, DPA= 1, 2-bis (diphenylphosphino) acetylene ...