Chemistry Letters

Hydrosilylation of Various Multiple Bonds by a Simple Combined Catalyst of a Tungstate Monomer and Rhodium Acetate

S Itagaki, H Sunaba, K Kamata, K Yamaguchi…

文献索引：Itagaki, Shintaro; Sunaba, Hanako; Kamata, Keigo; Yamaguchi, Kazuya; Mizuno, Noritaka Chemistry Letters, 2013 , vol. 42, # 9 p. 980 - 982

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被引用次数: 5

摘要

In the presence of a simple combined catalyst of a tungstate monomer (TBA 2 WO 4, TBA: tetra-n-butylammonium) and rhodium acetate (Rh 2 (OAc) 4), hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and furan derivatives efficiently proceeded, affording the corresponding hydrosilylation products in moderate to high yields (≥ 63% yields). In addition, the present system was also ...