Comparison of overtone-induced and electronic photochemistry of liquid tert-butyl hydroperoxide: supporting evidence for vibrational mode selectivity

JH Gutow, D Klenerman, RN Zare

文献索引：Gutow, J. H.; Klenerman, D.; Zare, R. N. Journal of Physical Chemistry, 1988 , vol. 92, # 1 p. 172 - 177

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被引用次数: 17

摘要

The spectroscopy and unimolecular decomposition kinetics of tert-butyl hydroperoxide have been studied both in neat liquid and diluted in carbon tetrachloride. The data show that the tail of a transition to a repulsive electronic state extends to 540 nm but it is insignificant at longer wavelengths. The peak cross section of the 6-0 0-H overtone of tert-butyl hydroperoxide at 535 nm is estimated to be 5-24 times more intense than the electronic ...