Diethyl-1-magnesium chloride methanephosphonate, A novel grignard reagent and its use in organic synthesis

P Coutrot, M Youssefi-Tabrizi, C Grison

文献索引：Coutrot, P.; Youssefi-Tabrizi, M.; Grison, C. Journal of Organometallic Chemistry, 1986 , vol. 316, p. 13 - 18

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被引用次数: 10

摘要

Summary Diethyl-1-magnesium chloride methanephosphonate was obtained by an exchange reaction between diethyliodo methanephosphonate and isopropylmagnesium chloride in THF at− 70 C. Reactions of this novel Grignard reagent with various electrophiles are described, and compared with those of the analogous lithium or copper derivatives. Diethyl-1-magnesium chloride methanephosphonate is especially reactive towards ...