Tetrahedron Letters

Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes

T Taniguchi, A Idota, S Yokoyama, H Ishibashi

文献索引：Taniguchi, Tsuyoshi; Idota, Atsushi; Yokoyama, Shin'Ichi; Ishibashi, Hiroyuki Tetrahedron Letters, 2011 , vol. 52, # 37 p. 4768 - 4770

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被引用次数: 17

摘要

Phosphorohydrazidates have been shown to work as radical precursors by iron-catalyzed aerobic oxidation to generate corresponding phosphonyl radicals. Generated radicals cause intermolecular addition to various alkenes in the presence of molecular oxygen to give β- hydroxyphosphonate compounds in good yield.