The oxidation of sulfides by chromium (V)

CR Jackson Lepage, L Mihichuk…

文献索引：Lepage, Carmela R. Jackson; Mihichuk, Lynn; Lee, Donald G. Canadian Journal of Chemistry, 2003 , vol. 81, # 1 p. 75 - 80

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被引用次数: 14

摘要

The mechanism for the oxidation of sulfides by [(me4-salen) CrV (O)(pyO)] CF3SO3, where me4-salen is 8, 8, 8', 8'-tetramethylsalen and pyO is pyridine N-oxide, has been investigated. Results from Hammett correlations on the rates of oxidation of substituted thioanisoles, frontier molecular orbital calculations, and product studies are consistent with a mechanism that is initiated by a single electron transfer to give a radical cation intermediate. Key ...