Ozonolysis of silyl diazo compounds and silyl ketones

A Sekiguchi, W Ando

文献索引：Sekiguchi,A.; Ando,W. Journal of the Chemical Society, Chemical Communications, 1979 , p. 575 - 576

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摘要

SILYL KETONES are of interest because of their chemical properties and their unique spectral behaviour.1 They must be prepared under relatively mild and neutral con- ditions to avoid cleavage of the silicon-carbonyl carbon b0nd.l Recently, we demonstrated a new method for the synthesis of silyl ketones possessing a functional group by the photosensitized oxygenation of silyl diazo compounds.2 Ozonolysis is one of the most efficient methods of cleaving carbon-carbon ...