The Journal of Organic Chemistry

Dye-sensitized photooxidation of silyl diazo compounds. Intramolecular oxygen transfer of carbonyl oxides

A Sekiguchi, Y Kabe, W Ando

文献索引：Sekiguchi, Akira; Kabe, Yoshio; Ando, Wataru Journal of Organic Chemistry, 1982 , vol. 47, # 15 p. 2900 - 2903

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被引用次数: 17

摘要

The dye-sensitized photooxidation of silyl diazo compounds produced the corresponding silyl ketones and silyl esters, and the latter may be formed by the rearrangement of silyl- substituted carbonyl oxides. The reactions of a carbonyl oxide with various silyl ketones were also studied. The dye-sensitized photooxidation of diphenyldiazomethane in the presence of silyl ketones gave silyl esters together with benzophenone by reactions of a ...