Bulletin of the Chemical Society of Japan

Direct conversion of arylamines to the corresponding halides, biphenyls, and sulfides with t-butyl thionitrate.

S Oae, K Shinhama, YH Kim

文献索引：Oae, Shigeru; Shinhama, Koichi; Kim, Yong Hae Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 7 p. 2023 - 2026

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被引用次数: 16

摘要

t-Butyl thionitrate have been found to be an excellent diazotizing reagent of arylamines in aprotic nonpolar media, affording eventually such products as aryl chlorides, aryl bromides, aryl iodides, biphenyls, and aryl methyl sulfides in the presence of CCl 4, CHBr 3, I 2, benzene, and dimethyl disulfide, respectively, via extrusion of N 2.

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