Palladium-nanoparticle-catalyzed 1, 7-palladium migration involving C–H activation, followed by intramolecular amination: regioselective synthesis of N 1- …

K Takagi, M Al-Amin, N Hoshiya…

文献索引：Al-Amin, Mohammad; Akimoto, Masayoshi; Tameno, Tsuyoshi; Ohki, Yuuta; Takahashi, Naoyuki; Hoshiya, Naoyuki; Shuto, Satoshi; Arisawa, Mitsuhiro Green Chemistry, 2013 , vol. 15, # 5 p. 1142 - 1145

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被引用次数: 17

摘要

A sulfur-modified gold-supported palladium material (SAPd) has been developed bearing palladium nanoparticles on its surface. Herein, we report for the first time the use of SAPd to affect a Pd-nanoparticle-catalyzed 1, 7-Pd migration reaction for the synthesis of benzotriazoles via C–H bond activation. The resulting benzotriazoles were evaluated in terms of their inhibitory activity toward indoleamine 2, 3-dioxygenase.