A new solvent system for recycling catalysts for chelation-assisted hydroacylation of olefins with primary alcohols

DH Chang, DY Lee, BS Hong, JH Choi…

文献索引：Chang, Duck-Ho; Lee, Dae-Yon; Hong, Boo-Sun; Choi, Jun-Hack; Jun, Chul-Ho Journal of the American Chemical Society, 2004 , vol. 126, # 2 p. 424 - 425

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被引用次数: 29

摘要

C−H bond activation by transition metal catalysts is one of the current interests in organic synthesis. 1 Particularly, hydroacylation through aldehydic C−H bond activation provides an efficient synthetic method for preparing ketones. 2 In the course of our studies on chelation-assisted hydroacylation, 3 a one-pot protocol to obtain ketones from primary alcohols and olefins was devised using a cocatalyst system of a rhodium complex and 2-aminopyridine. 4 ...