A model study toward the total synthesis of N-deacetyllappaconitine

DF Taber, JL Liang, B Chen, L Cai

文献索引：Taber, Douglass F.; Cai, Lisi Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4887 - 4888

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被引用次数: 15

摘要

A model study leading to the preparation of the AEF rings of N-deacetyllappaconitine is described. The conjugate addition to the α-alkyl cyclohexenone 10 proceeded with high diastereocontrol. The Mannich cyclization of 16 to 4 was accomplished by heating with