Cationic Carboxylato Complexes of Dirhodium (II) with Oxo Thioethers: Catalysts for Silane Alcoholysis under Homogeneous and Liquid??Liquid Biphasic Conditions
…, M Basato, M Brichese, L Ronconi…
文献索引：Biffis, Andrea; Basato, Marino; Brichese, Marianna; Ronconi, Luca; Tubaro, Cristina; Zanella, Alessandra; Graiff, Claudia; Tiripicchio, Antonio Advanced Synthesis and Catalysis, 2007 , vol. 349, # 16 p. 2485 - 2492
Abstract A set of cationic dirhodium (II) complexes with oxo thioethers was prepared and employed as catalysts for the silane alcoholysis reaction. The complexes were found to be highly active under homogeneous conditions, both in the absence and in the presence of a solvent, including coordinating solvents such as N, N-dimethylformamide; the catalysts could be conveniently employed in concentrations as low as 0.01 mol%, and a maximum TON of ...
