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Comparison of 9-Phenylfluorenyl and Triphenylmethyl in the Decomposition of Azo Compounds1a, b

SG Cohen, F Cohen, CH Wang

文献索引:Cohen,S.G. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 1479 - 1484

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被引用次数: 11

摘要

Received Sovewiber lY, 1061 p-Nitrophenylazo-, o-nitrophenylazo-, and 2, 4- dinitrophenylaso derivatives of 9-phenylfluorene and triphenylmethane have been prepared and the kinetics of their decomposition in toluene has been studied. In each case the phenylfluorenyl derivative decomposed more rapidly than the corresponding triphenylmethyl derivative, and with lower activation energy. This is ascribed to and cited as evidence for ...