High-pressure studies. 25. One-bond azo initiators. Thermal decomposition of substituted (phenylazo) triphenylmethanes

RC Neuman Jr, GD Lockyer Jr

文献索引：Neuman, Robert C.; Lockyer, George D. Journal of the American Chemical Society, 1983 , vol. 105, # 12 p. 3982 - 3987

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被引用次数: 17

摘要

Abstract: Rate constants for thermal decomposition of the p-N02, m-N02, m-methyl, p-methyl, and unsubstituted (pheny1azo) triphenylmethane (1) in octane and several aromatic solvents have been determined and correlated with medium viscosity. Decomposition rate constants for pN02 and unsubstituted 1 in n-alkane solvents previously reported have been reanalyzed. These data indicate that p scission of intermediate diazenyl radicals is an ...