Direct and Stereoselective Preparation of Optically Active 1, 3-Dioxolanes from the Corresponding Chiral Styrene Oxides.

…, T Takai, T Yamada, K Imagawa, T Mukaiyama

文献索引：Nagata; Takai; Yamada; Imagawa; Mukaiyama Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 9 p. 2614 - 2616

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被引用次数: 23

摘要

In the presence of a catalytic amount of titanium (IV) chloride, optically active styrene oxide and its analogs are directly converted into the corresponding acetals such as acetonides or cyclopentylidene acetals keeping up high to complete optical purity on the treatment with ketones.