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Metal promoted cyclization. 18. Novel cyclialkylation reactions of (. omega.-halo-1-alkenyl) metal derivatives. Synthetic scope and mechanism

E Negishi, LD Boardman, H Sawada…

文献索引:Negishi,E.; Boardman,L.D.; Sawada,H. Journal of the American Chemical Society, 1988 , vol. 110, p. 5383

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被引用次数: 87

摘要

Conclusion. In general, solid-state five-coordinated tin structures lie along the Berry pseudorotational coordinate as an expression of their structural nonrigidity, similar to that found for other elements of groups 14 and 15 that have been studied. Implications are that in going down a particular family, nonrigid character