Journal of Organometallic Chemistry

The hydroboration-oxidation of the isomeric trimethylsilylcyclo-hexenes and the isomeric trimethylsilylcyclopentenes.

M de Jesus, O Rosario, GL Larson

文献索引：de Jesus,M. et al. Journal of Organometallic Chemistry, 1977 , vol. 132, p. 301 - 320

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被引用次数: 10

摘要

Abstract The isomeric trimethylsilyl substituted cyclohexenes, 1-trimethylsilylcyclohexene, 3- trimethylsilylcyclohexene, and 4-trimethylsilylcyclohexene and the analogous trimethylsilyl substituted cyclopentenes, 1-trimethylsilylcyclopentene, 3-trimethylsilylcyclopentene and 4- trimethylsilylcyclopentene have been hydroborated and oxidized under kinetic and thermodynamic conditions. The hydroborating agents used were borane and ...