Palladium-Catalyzed Alkoxyamination of Alkenes with Use of N-Fluorobenzenesulfonimide as Oxidant

…, PA Sibbald, CF Rosewall, FE Michael

文献索引：Lovick, Helena M.; Michael, Forrest E. Journal of the American Chemical Society, 2010 , vol. 132, p. 1249 - 1251

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被引用次数: 32

摘要

A Pd-catalyzed alkoxyamination of protected aminoalkenes promoted by N- fluorobenzenesulfonimide is described. This mild transformation allows the direct formation of ethers from carbon− carbon double bonds. An unusual switch from exo to endo selectivity in polar solvents was discovered, allowing the selective formation of either regioisomer by careful choice of reaction conditions.