前往化源商城

Organotellurium Chemistry: Remarkably Facile Preparation of Benzo??1, 3??tellurazoles

NC McMullen, FR Fronczek…

文献索引:McMullen, Nathan C.; Fronczek, Frank R.; Junk, Thomas Journal of Heterocyclic Chemistry, 2013 , vol. 50, # 1 p. 120 - 124

全文:HTML全文

被引用次数: 3

摘要

Abstract Benzo-1, 3-tellurazoles carrying alkyl or aryl substituents in position 2 were prepared in a facile two-step sequence, starting with readily available 2-haloanilines. This approach relies on the preparation of bis (2-aminophenyl) ditellurides by nucleophilic halide displacement from 2-haloanilines with sodium telluride in N-methylpyrrolidone. Subsequent reductive cyclization with carboxylic acid halides or carboxylic anhydrides furnished ...