Organotellurium Chemistry: Remarkably Facile Preparation of Benzo??1, 3??tellurazoles

NC McMullen, FR Fronczek…

Index: McMullen, Nathan C.; Fronczek, Frank R.; Junk, Thomas Journal of Heterocyclic Chemistry, 2013 , vol. 50, # 1 p. 120 - 124

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Citation Number: 3

Abstract

Abstract Benzo-1, 3-tellurazoles carrying alkyl or aryl substituents in position 2 were prepared in a facile two-step sequence, starting with readily available 2-haloanilines. This approach relies on the preparation of bis (2-aminophenyl) ditellurides by nucleophilic halide displacement from 2-haloanilines with sodium telluride in N-methylpyrrolidone. Subsequent reductive cyclization with carboxylic acid halides or carboxylic anhydrides furnished ...